Friday, August 24, 2012

Test Chapter ATOMIC STRUCTURE Class XI (Chemistry) CBSE/WB/ISC



Test Chapter ATOMIC STRUCTURE

Subject: Chemistry                                                        Total Marks: 25
Class: XI                                                                      Max time: 60 minutes

  1. Write the difference between emission spectrum and absorption spectrum. (1)
  2. Why the energy of electron in an atom is negative?                                      (1)
  3. What is Hund’s rule of maximum multiplicity? Explain with examples.     (1)
  4. Two electrons occupy the same orbital together despite the repulsions of like electrostatic charges.                                                                                             (1)
  5. Write the complete symbol for the atom with the given atomic number
(Z) and atomic mass (A).
(a)    Z = 17  A = 35
(b)   Z = 4    A = 9                                                                           (1)
6.  Which of the following ions are unlikely and Why? K+ and I3-                 (1)
7.  Explain why the electronic configuration of Cr is [Ar] 3d54s1
and not [Ar] 3d44s2                                                                                (1)
8. State Pauli’s exclusion principle.                                                                (1)
9.  Calculate the total number of electrons present in 2g of CH4.                     (2)
10. Write the differences between cathode rays and anode rays.                     (2)
11. Calculate the wave number of the line of frequency 4 x 1014  s-1                (2)
12. Write the main postulates of Planck’s Quantum theory.                             (2)
13. If the velocity of electron in Bohr’s first orbit is 2.19 x 108 m/s.
Calculate the de- Broglie wavelength associated with it.                             (2)
14. Explain line spectrum of Hydrogen.                                                           (2)
15. Using s, p, d notations, describe the orbital with the following
quantum numbers.
                 a) n = 1, l = 0
                 b) n = 3, l = 1
                 c) n = 4, l = 2
                 d) n = 4, l = 3                                                                                  (2)                               
16. (i) An atomic orbital has n = 3. What are possible values of l and ml ?
     (ii) List the quantum numbers (ml and l) of electrons for 3d orbital.              (3)
     (iii) Which of the following orbitals are possible?
                             1p, 2s, 2p and 3f



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