THERMODYNAMICS
BSC-II
1.
An iron cube at a temperature of 400o C is dropped into
an insulated bath containing 10kg water at 25o C. the water
finally reaches a temperature of 50o C at steady state. Given
that the specific heat of water is equal to 4186 J / kg K. find the entropy
changes for the iron cube and the water. Is the process reversible? If so why?
2.
Derive Entropy
of a mixture of Ideal Gases
3.
Calculate the
entropy changes of an Ideal Gas in different processes?
4.
Derive the Entropy changes for a
reversible process.
5.
Prove that Entropy is a Property.
6.
Explain Clapeyron-Clausius
Equation and also give its derivation.
7.
Explain the concept of Fugacity?
8.
Define Kelvin Planck and Clausius statements of the second law of
Thermodynamics.
9.
A Carnot engine has the same efficiency (i) between 100 K and 500 K and
(ii) between T K and 900 K. Calculate the temperature T of the sink.
10. An ideal gas is
heated from temperature T1 to temperature T2 by
keeping its volume constant. The gas is expanded back to its initial
temperature according to the law PVn = constant. If the entropy
changes in the two processes are equal, find the value of n in terms of the
adiabatic index γ
11. A Carnot engine
converts one fifth of the heat input into work. If the sink temperature is
reduced by 80o C, the efficiency gets doubled. Find the source
and the sink temperature. Also give the consequences of the Carnot cycle.
12. Carnot engine
working between a source temperature of T2 and sink temperature
of T1 has efficiency of 25%. If the sink temperature is reduced
by 20o C, the efficiency is increased to 30%. Find the source
and the sink temperature.
13. A Carnot engine
converts one sixth of the heat input into work. If the sink temperature is reduced
by 62o C, the efficiency gets doubled. Find the source and the
sink temperature.
14. Calculate the
maximum efficiency of an engine operating between 120o C and 35o C
15. Define Carnot
Theorem and also give its proof.
16. Calculate the net
efficiency of a Heat Engine?
17. Explain Cyclic
Process with example.
18. Define the spontaneous
processes with example
19. Discuss the
limitations of the first law of Thermodynamics.